复方化学消毒剂中苯扎氯铵的高效液相色谱测定   总被引：1，自引：0，他引：1  

刘雯雯  张瑾  乔俊琴  练鸿振 《岩矿测试》2011,30(6):677-682

建立了一种测定复方化学消毒剂中苯扎氯铵成分十二烷基二甲基苄基氯化铵、十四烷基二甲基苄基氯化铵和十六烷基二甲基苄基氯化铵的反相离子对高效液相色谱法。色谱柱为Platisil ODS(5μm,250 mm×4.6mm),流动相为甲醇-0.2 mol/L己烷磺酸钠(含1%三乙胺,V/V,用高氯酸调节至pH=6.0,体积比85∶15),紫外220 nm检测。用己烷磺酸钠作为离子对试剂,增强了苯扎氯铵成分的保留,三乙胺作为扫尾剂,通过抑制固定相表面残存的硅羟基对苯扎氯铵成分的吸附,减少了色谱峰拖尾。3种苯扎氯铵成分分离良好,标准曲线的线性范围分别为0.002～5 mg/mL、0.005～10 mg/mL和0.005～10 mg/mL,检测限分别为0.0005 mg/mL、0.001mg/mL和0.001 mg/mL。方法具有良好的准确度和精密度,在测定低浓度样品时优势明显。实际用于测定苯扎氯铵消毒液和医用消毒纸巾中3种苯扎氯铵成分的含量,回收率为99.3%～104.1%,日内和日间测定相对标准偏差(RSD)均小于2.0%。  相似文献   

Correlation of main physicochemical parameters of some groundwater in northern Serbia     

Sanja Mrazovac  Mirjana Vojinović-Miloradov 《Journal of Geochemical Exploration》2011

The geothermal waters of the first and the shallowest groundwater system of the Province of Vojvodina in northern Serbia, south part of the Pannonian Basin, are characterized by elevated temperatures (between 25 and 85 °C) and elevated gas content (above 1 Nm³/m³) with a high methane content (average about 94% of total gases). These methane-containing waters are particularly abundant in the Central part of the province between Danube and Tisa rivers. Dominant ions in these waters are sodium and bicarbonate, but the waters also contain significant amounts of calcium, magnesium, potassium, chloride, and ammonium. Components that are of balneological significance include iodine, bromine, fluorine, strontium, lithium, barium, and metasilicic and metaboric acids. Based on statistical analysis, a strong positive correlation is generally observed in about 9.2% cases. A slightly lower correlation appears in about 42.2%, and negative correlation coefficient appears in about 48.6% cases. The dendrogram of the cluster analysis built on the wells shows three main groups. There is the cluster of (Na⁺)_aq, (Cl⁻)_aq and (HCO₃⁻)_aq. The second aggregation is (NH₄⁺)_aq/(NH₃)_aq. The third group includes (Mg²⁺)_aq, (Ca²⁺)_aq, (Fe³⁺)_aq, (Sr²⁺)_aq, (Pb²⁺)_aq, and (Zn²⁺)_aq.  相似文献   

安徽铜山矿区花岗闪长斑岩矿物化学 特征及成因探讨     

李大鹏 《地质与勘探》2011,47(5):865-875

由于前人对与安徽铜山铜矿床成矿关系密切的花岗闪长斑岩的矿物化学成分变异机制研究较为欠缺,本文对其进行了详细的矿物化学分析,并结合前人获得的岩石化学资料进行了研究,结果表明,岩体中黑云母具有富MgO(13.13%～17.19%)、FeOT(15.33%～17.42%),贫Al2O3(13.27%～13.74%)、高TiO2(3.11%～4.66%)的特点,其MF值为0.57～0.66,Fe/(Fe+Mg)值为0.48～0.57,主要为金云母;角闪石具有高FeOT(13.50%～15.33%)和Al2 O3(6.26%～13.74%)、低SiO2(36.21%～46.91%)的特点,主要为镁质角闪石;辉石中的Al2 O3的含量变化较大(0.17%～1.08%),Na2 O含量普遍较低。黑云母、角闪石和辉石特征表明,铜山花岗闪长斑岩的母岩浆属于亚碱性系列的壳幔混染型岩浆,它们形成于造山作用晚期,并有向非造山环境过渡的趋势。利用黑云母-角闪石温压计得出成岩温度为750～900℃,成岩压力为3.2×108～4×108Pa,相应的成岩深度约为10.56～13.2 km;利用黑云母Fe3+-Fe2+-Mg三元图解,显示了相对较高的氧逸度;另外,相比于长江中下游其它侵入岩,铜山花岗闪长斑岩具有成岩深度较深,氧逸度相对较低的特点。  相似文献   

高浓度化学浆液的研制与应用效果          下载免费PDF全文

朱效中  朱学光 《探矿工程》2011,38(10):60-62

淮北某煤矿因第四含水层水量过大,通过F5断层导入采煤工作面,使采煤生产陷入停顿。为解决采煤工作面涌水量过大问题,研制了高浓度化学浆液,经钻孔注浆收到良好的止水效果,使近200万t煤炭资源恢复开采,取得了很好的经济和社会效益。  相似文献   

碱金属离子及碱溶液对膨润土性能影响的研究进展     

叶为民  郑赈济  陈宝  陈永贵 《国外铀金地质》2011,(4):221-227

基于前人有关膨润土在碱性环境下的室内试验和数值模拟的研究结果 ,重点阐述了碱金属离子及碱溶液对膨润土矿物成分、微观结构、膨胀性和渗透性等方面的影响,讨论了温度、pH值与溶液浓度等对上述过程的影响。碱金属离子及碱性溶液不仅可交换膨润土中蒙脱石层间阳离子,而且可溶解膨润土中的蒙脱石,生成非膨胀性矿物,并随着温度和pH值升高,蒙脱石被溶解程度增加,从而导致了膨润土膨胀力减小,且随着温度、溶液浓度及pH值的增加,膨胀力削弱程度加强;同时,膨润土与碱金属离子及碱溶液接触时孔隙增多,进而渗透性增强,随着温度和溶液浓度增加,渗透性也明显增强。数值模拟可实现膨润土与碱性溶液长期接触时发生的矿物成分及渗透性变化的预测。高温、不同pH值的低碱性溶液及其耦合作用对膨润土的矿物化学成分、微观结构、膨胀力和渗透性的影响及机理研究应该是今后研究的重点。  相似文献   

河南嵩县香春沟石英脉型钼矿的矿石及地球化学特征     

丁慧霞  陈文林  庞镇山  周奇明 《矿产与地质》2011,25(1):23-28

香春沟钼矿床是河南省新发现的唯一中型石英脉型钼矿床.主要矿石类型为石英脉型钼矿石,具有超酸高钾的特点,矿石构造结构简单,矿区有用矿物主要是辉钼矿,其粒度细小,不易与脉石分离.文章通过分析区内元素的地球化学特征,为寻找该类型钼矿床提供参考.  相似文献   

泉州城市表层土壤重金属的赋存形态及污染评价   总被引：3，自引：0，他引：3  

林燕萍  胡恭任  于瑞莲  张雪琴 《矿物岩石》2011,31(2)

本文采用改进的BCR连续提取法研究泉州市区表层土壤中17种重金属的形态分布特征,并运用地积累指数Igeo法、潜在生态危害指数法、次生相与原生相分布比值法(RSP)评价土壤中重金属元素的潜在生态危害。结果表明,Li,Ti,Fe,Sc,V,As,Sb,Sn主要以残渣态存在;Cr,Ni,Cu,Zn,Bi在可氧化态中占有大比例,但仍以残渣态为主;Pb以可还原态为主;Mn,Cd,Co在可还原态和残渣态中占有较大比例。根据地累积指数法和RSP,泉州土壤受到不同程度的Sc,Co,Ni,Cu,Cd,Sb,Pb污染;潜在生态危害指数表明泉州市城区受到轻微生态危害。  相似文献   

拉萨市夏季大气降尘单颗粒矿物组成及其形貌特征   总被引：3，自引：0，他引：3       下载免费PDF全文

张学磊  邬光剑  岳雅慧  张成龙 《岩石矿物学杂志》2011,30(1):127-134

应用带能谱的电子扫描电镜(SEM-EDX)对拉萨市夏季正常天气下收集的大气自然沉降气溶胶样品进行分析,研究了拉萨市大气降尘矿物组成和各种物相形貌特征信息。拉萨市大气颗粒物含有硅酸盐颗粒、富钙颗粒、富铁颗粒、富碳颗粒(燃煤飞灰颗粒和燃油飞灰颗粒)和植物残体颗粒。根据颗粒物数量统计发现拉萨市大气颗粒物以硅酸盐颗粒为主,富钙颗粒和富铁颗粒次之,需要指出的是以燃油飞灰为主的富碳颗粒已占到一定比重,说明以燃油为主的机动车尾气对拉萨大气污染在加强。研究结果表明,大气降尘矿物成分及其形貌特征可以用作判定污染物来源的重要标志,拉萨大气中颗粒来源的多样性决定了治理措施也应综合进行。  相似文献   

藏南拉木由塔锑(金)矿床S、Pb同位素组成及指示意义   总被引：1，自引：1，他引：0  

杜泽忠  顾雪祥  李关清  章永梅  程文斌  景亮兵  张兴国 《现代地质》2011,25(5):853-860

西藏拉木由塔锑(金)矿床位于藏南Sb - Au成矿带东段,矿(化)体主要赋存于中侏罗统遮拉组地层与辉绿(玢)岩脉接触带上.在分析该矿床成矿地质条件的基础上,系统研究了矿石硫、铅同位素组成特征,并通过与区域成矿带中典型矿床硫、铅同位素组成的对比分析,探讨了矿床成矿物质来源.研究表明矿石硫化物的硫同位素组成变化范围较窄,成...  相似文献   

The Impact of Aqueous Medium on Gas Yields and Kinetic Behaviors of Hydrogen Isotope Fractionation during Organic Matter Thermal Degradation     

LU Shuangfang  WANG Min  XUE Haitao  LI Jijun  CHEN Fangwen  XU Qingxia 《《地质学报》英文版》2011,85(6):1466-1477

In order to recognize the impact of aqueous medium on gas yields and the kinetic behaviors of hydrogen isotope fractionation during organic matter thermal degradation, the gold tube apparatus was used to conduct thermal simulation experiments by mixing the nC18 with the water of different properties and proportions. The yields of natural gas components, the relation among hydrogen isotope composition of each component and the experimental temperatures vs. heating rates have been obtained, and the results indicate that under the higher temperature conditions, the hydrous experiment has obvious impact on gas yields, such as when more water is added, higher amounts of hydrocarbon gas and H2 are yielded, and the existence of water obviously prolongs the temperature interval with the existence of heavy hydrocarbon gas. It also shows that the hydrogen isotope of hydrocarbon gas generated by the hydrous experiment is obviously lighter than that generated by the anhydrous experiment, and with the increasing amount of added water, the δD value of hydrocarbon gas gradually decreases. Compared with gas yields, the variation of δD value is more sensitive to aqueous medium in the thermal simulation experiment. However, compared with the amount of the added water, the aqueous medium property has smaller impact on the gas yields, which still shows the inherit effect on hydrogen isotope composition of aqueous medium. Through the model simulation and the isotope fractionation behavior analysis, it is validated that the hydrogen isotope fractionation process can be well described by the chemical kinetic model. The difference of reaction fraction of normal methane and D-containing methane is large, corresponding to the same activation energy. The content of normal methane is obviously higher in the part with lower activation energy, while the content of D-containing methane is higher in the part with higher activation energy. Therefore, it will result in larger hydrogen isotope fractionation amplitude, and the δD values will be more sensitive to the variation of maturity. Meanwhile, the average activation energy of methane generation from nC18 in the hydrous experiment is higher than that in the anhydrous experiment, and the greater amount of added water, the larger the average activation energy of methane generation reaction. This has laid foundation for its exploratory application in the study of gas reservoir forming history and the gas-source correlation, which indicates the research and application prospects in this orientation.  相似文献